"A fool with a tool, is still a fool."
TFS is a great tool, but still it doesn't tell you how to do things. To close the missing gaps you need practices and a framework (like Scrum). Luckily, Scrum.org and Microsoft started the Professional Scrum Developer Program (PSD), which trains people in all three topics.
An ideal combination:
Additionally this will be the only official course on Visual Studio 2010 team features and Team Foundation Server 2010 autorized by Microsoft (no MOC courses).
Since this summer, I 'm certified as Professional Scrum Master (PSM) and as one of the Professional Scrum Developer Trainers (PSDT) that will be teaching the course.